• 作者： 郭慶輝; 陳敦禮
• 作者服務機構： Department of Chemistry, Tamkang College of Arts & Sciences, Tamsui, Taipei Hsien, Taiwan 251, ROC
• 中文摘要： The carbonyl stretching vibration of monocarboxylic acid in CCl4 solution has of this investigated. We introduce a new “m-factor” to study the polymerization of this simple RCOOH system. The value of “m-factor” was evaluated and tested in different concentrations and temperatures. Three classes of acid polymers were found as followings: linear dimer in class I (m…2); linear and cyclic dimers in class II (m…4); linear, cyclic dimers, and linear trimer in class III (m…8). A linear relationship between log K1 and (ε—1)/(2ε+1) was found.
• 英文摘要： --
• 中文關鍵字： --
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