- 作者: 王信二 ; 劉緒宗 ; 李錦祥 等
- 作者服務機構: 台灣大學化學系
- 中文摘要: Reaction of copper(I) chloride with 2,2-bis(diphenylphosphinomethyl)-1-phenylthiopropane P/sub 2/S produced a dimeric species((P/sub 2/S)CuCl)/sub 2/ (2). Treatment of 2 with silver nitrate in acetonitrile gave a hexameric crystalline metal complex. lbrace.((P/sub 2/S)Cu(CH/sub 3/CN))/sub 6//sup +/ 6NO/sub 3//sup -/.rbrace. (4), which had a"cyclodextrin-type" structure. A linear polymeric copper complex ((P/sub 2/S)Cu(NO/sub 3/))/sub n/ was obtained by recrystallization of 4 in chloroform. These complexes were characterized by single crystal analyses, and their coordination behaviors in solution are discussed.
- 英文摘要: --
- 中文關鍵字: Tripodal Phosphine; Copper(I); Synthesis; Coordination; Complex; Copper Chloride; Cyclodextrin Type; Metal Complex
- 英文關鍵字: 三腳基膦;銅;合成;配位;錯合物;氯化亞銅;環糊精型;金屬錯合物