- 作者: 吳西南 ; 林育民 ; 翁義綱
- 作者服務機構: 中興大學化學系
- 中文摘要: Upon irradiation at room temperature, the title compound 1 isomerized selectively and quantitatively into a cyclobutanedione (2) which underwent quantitatively bisdecarbonylation to afford a cyclohexadiene. Thermolysis of 2 produced 1 and a bicyclo [ 2.2.1 ] heptenone (4): Compound 4 was prepared in 70% yield by irradiation of 1 in refluxing dry toluene.
- 英文摘要: --
- 中文關鍵字: Photochemistry; Thermolysis; Decarbonylation; Temperature; Cyclobutanedione; Cyclohexadiene
- 英文關鍵字: 光化學;熱裂解;去羰化;溫度;環丁二酮;環己二烯