- 作者: 陳時仁 ; 施正雄
- 作者服務機構: 台灣師範大學化學系
- 中文摘要: Poly(styrene/divinyl benzene) with cryptand 22 as an anchoring group was synthesized and applied as a bifunctional packing material for the separation of both cations and anions. At pH<2, the resin can be protonated and applied as an anion exchanger for the separation of anions; with water as eluent, inorganic anions such as F/sup -/, Cl/sup -/, Br/sup -/, NO/sub 3//sup -/, I/sup -/ were well separated. After deprotonation at pH>10, the resin became a cation exchanger and successfully separated alkali metal ions such as Li/sup +/, K/sup +/ and Cs/sup +/ with methanol as eluent. The effects of solvents, flow rate and temperature on the separation of various ions were also investigated.
- 英文摘要: --
- 中文關鍵字: Cryptand; Ion Separation; Stationary Phase; Chromatographic Column; Ion-Exchange Chromatography
- 英文關鍵字: 離子分離;靜止相;層析柱;離子交換層析