- 作者: 毛士軒, 劉世安, 廖芬鈴, 許拱北
- 作者服務機構: Department of Chemistry, National Cheng Kung University, Tainan 701, Taiwan, R.O.C.
- 中文摘要: The direct mixing of CoCl2, sodium 2,6-pyridinedicarboxylate (Na2(2,6-pda)), KSCN, and 1,2-bis(4- pyridyl)ethane (bpye) in water at the ambient temperature afforded purple crystals readily. The crystal structure, as determined by X-ray diffraction crystallography, consists of discrete inorganic [Co2(η3-2,6-pda)2(μ-SCN)2(H2O)2] and organic bpye molecules. Adjacent dicobalt molecules are connected via intermolecular hydrogen bonds, to form one-dimensional hydrophobic channels in the solid state, which serve as a host framework to incarcerate bpye guests inside. Every organic molecule attaches to four adjacent inorganic species via arene-arene interactions. The facile approach in assembling the dicobalt and bpye molecules together into an inorganic clathrate is demonstrated.
- 英文摘要: --
- 中文關鍵字: Clathrate; Cobalt; Pyridinedicarboxylate; 1,2-Bis(4-pyridyl)ethane; Structure.
- 英文關鍵字: --