- 作者: 張智亮,陳焜銘
- 作者服務機構: Department of Chemistry, National Taiwan Normal University, Taipei, Taiwan 116, R.O.C.
- 中文摘要: Diastereoselective allylation of imine derived from N-glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.
- 英文摘要: --
- 中文關鍵字: Diastereoselective; Chiral auxiliary; Allylation; Homoallylic amine; Stereoselectivity; Camphorpyrazolidinone.
- 英文關鍵字: --