- 作者: 林遵遠
- 作者服務機構: Department of Chemistry, Soochow University, Shilin, Taiwan, 111
- 中文摘要: The chromic acid oxidation of cyclohexanone catalyzed by picolinic acid in water undergoes a change from first=to zero-order dependence in both cyclohexanone and acidity. The mechanism proposed indicates the formation of an intermediate C1 by picolinic acid and chromic acid. Then C1 would react with enol form of cyclohexanone to give another intermediate C2. C2 finally cleaves into products.
- 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --