- 作者: 溫聰明
- 作者服務機構: 成功大學化學系
- 中文摘要: The chemical thermodynamic properties C/sub p//sup 0/, .DELTA.H/sub f//sup 0/, S./sup 0/,.DELTA.G/sub f//sup 0/, and K/sub p/ of gaseous perfluoro n-alkanes, F.single bond.(CF/sub 2/)/sub n/.single bond.F(2.ltoreq.n.ltoreq.10), have been calculated from 298.15 to 1000 K using the Benson method with C/sub p//sup 0/=a+b/T+c/(T/sup 2/), C/sub p//sup 0/=a'+b'T+c'/(T/sup 2/) and C/sub p//sup 0/=a"+b"T+c"T/sup 2/. Better results are obtained for C/sub p//sup 0/=a+b/T+c/T/sup 2/. The calculated chemical thermodynamic properties of C/sub 2/F/sub 6(g)/ are in excellent agreement with the literature data of Stull, Westrum, and Sinke under IBM/PC microcomputer with STEP data base management system.
- 英文摘要: --
- 中文關鍵字: Perfluoro N-Alkanes; Benson Method; Enthalpy Of Formation; Entropy; Gibbs Energy Of Formation; Heat Capacity; Thermodynamic Properties
- 英文關鍵字: 全氟正鏈烷;生成焓;熵;合成吉佰能;熱容量;熱力學性質