- 作者: 魏和祥
- 作者服務機構: 淡江大學化學系
- 中文摘要: Mossbauer and magnetic studies on the spin-state transitions in various complexes of iron(II) and iron(III) ions have received considerable attention. The present account deals with some examples of the effects of intraligand substitution and sample size on the spin-state transitions of /sup 5/T/sub 2/.arrlr./sup 1/A/sub 1/ for iron(II) and /sup 6/A/sub 1/.arrlr./sup 2/T/sub 2/ for Iron(III)-complexes. A new instance of/sup 3/T/sub 1/.arrlr./sup 5/T/sub 2/ spin-crossover Fe(II)-complex is reported.
- 英文摘要: --
- 中文關鍵字: Mossbauer Effect; Spin Crossover Iron Complex; Magnetic Property; Intraligand Substitution; Spin State Transition
- 英文關鍵字: 梅斯堡效應;自旋交叉鐵錯化合物;磁性質;配位基內取代;自旋態轉移