- 作者: 易光輝、李錦祥、黃守齡、王瑜
- 作者服務機構: Department of Applied Cosmetology, Hungkuang University Shalu, Taichung, Taiwan 433, R.O.C.
- 中文摘要: Treatment of Pt(PPh3)4 with N,N-dimethylthiocarbamoyl chloride, Me2NC(=S)Cl, in dichloromethane at -20 °C processes the oxidative addition reaction to produce platinum complex [Pt(PPh3)2(η1-SCNMe2)(Cl)], 2 with releasing two triphenylphosphine molecules. The 31P{1H} NMR spectra of complex 2 shows the dissociation of the triphenylphosphine ligand to form diplatinum complex [Pt(PPh3)Cl]2(μ,η2-SCNMe2)2, 3 in which the two SCNMe2 ligands coordinated through carbon to one metal center and bridging the other metal through sulfur. Complex 2 is characterized by X-ray diffraction analysis.
- 英文摘要: --
- 中文關鍵字: N,N-dimethylthiocarbamoyl; Intermolecular; Dissociation; Platinum; X-ray diffraction.
- 英文關鍵字: --