第6卷‧第3期,
198207
, pp. 279-287
從乙烯二矽烷捕捉碳一矽雙鍵中間體
- 作者:
劉兆玄
- 作者服務機構:
國立清華大學化學系
- 中文摘要:
本文對捕捉不隱定的碳一矽雙鍵中間體的討論分為兩方面:(1)用有機化合物來捕捉,及(2)用有機金屬化合物來捕捉。全文主要部份是根據作者近年來從乙烯二矽烷中用過渡金屬羰化合物捕捉碳一矽雙鍵中間體的研究工作而寫成。在討論的過程中,簡單的背景資料及有關此方面最近的重要進展也作了簡單的介紹。
- 英文摘要:
Trapping the short-lived carbon-silicon doubly bonded species is discussed along two lines: by organiccompounds and by transition metal compounds. The major part of this paper is written on the basis of theathor's own recent work, mainly concerning the attempt of trapping C=Si intermediates from vinyl dis-ilanes by transition metal carbonyls. A brief historical background and the most recent activities in thisarea are also introduced along the line of discussion.
- 中文關鍵字:
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- 英文關鍵字:
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