- 作者: 陳麟慶; 吳信昇
- 作者服務機構: Graduate Institute of Pharmaceutical Science, Kaohsiung Medical College, Kaohsiung, Taiwan 800, R.O.C.
- 中文摘要: Acylation of the .alpha.-trimethylsilylallyl phenyl sulphide (2) by reaction with the acid chloride (3), catalyzed by aluminium chloride in CH/sub 2/Cl/sub 2/ at -78.degree.C, gave methyl 9-oxo-12-phenylthio-11-dodecene (4). Hydrolysis of (4) followed by aldol condensation gave 2-(6-methoxycarbonylhexyl)-cyclopent-2-en-1-one (6).
- 英文摘要: --
- 中文關鍵字: Regioselective .gamma.-acylation; base-catalysed silylation.
- 英文關鍵字: Regioselective .gamma.-acylation; base-catalysed silylation.