- 作者: Hsin-Pei Chen, Rong-Zhi Ku and Shiuh-Tzung Liu
- 中文摘要:
Department of Chemistry, National Taiwan University, Taipei, Taiwan 106, R.O.C.
Diamino-carbene ligand transfer between various metal ions is studied, particularly with Pd(II) to Rh(I), Rh(I) to Au(I). Reactions of various carbene complexes with AgPF6 result in the cleavage of the M=C bond to give the protonated carbene species, imidazolidin-2-ylidinium salt, indicating the presence of free carbene ligand in the reaction medium. When the carbene transfer process was carried out in tetrahydrofuran, the polymerization of tetrahydrofuran occurred. - 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --