- 作者: 林志彪
- 作者服務機構: Fu-Jen Catholic University, Chemistry Department, Taipei, Taiwan 242
- 中文摘要: Some halo or mercaptide bridge palladium (II) dimers, [Pd(S/sub 2/CNR/sub 2/)X]/sub 2/ (R=ibutyl, X=Cl, Br, I, S-ethyl and S-t-butyl) were studied by variable temperature /sup 1/H nmr spectroscopy. Line shape changes of the chloro and bromo bridged dimers were interpretated by the solvolytic breaking of the Pd-X bond, while mercaptide bridged complexes were explained in terms of slow N-C single bond rotation. The results consist with the strengthness of the class b metal ion with various soft donor ligands.
- 英文摘要: --
- 中文關鍵字: Palladium dimers; nmr.
- 英文關鍵字: Palladium dimers; nmr.