- 作者: 林遵遠 ; 傅明仁 ; 張世春 ; 林裕勝
- 作者服務機構: 東吳大學化學系
- 中文摘要: The rate constants for the electron transfer of samarium diiodide to 2-heptanal, 2-methyl valeraldehyde and diphenyl sulfoxide were obtained for the first time. The reaction is first order in these substrates and there are hints that the reaction rate has a strong steric dependence. HMPA exhibited a profound catalytic effect but t-BuOH did not. The effect of temperature on reaction rates was also obtained.
- 英文摘要: --
- 中文關鍵字: Samarium Diiodide; Carbonyl Compound; Sulfoxide; Electron Transfer
- 英文關鍵字: 二碘化釸;羰基化合物;亞;電子轉移