- 作者: 林遵遠
- 作者服務機構: Department of Chemistry, Soochow University, Taipei, Taiwan, R.O.C.
- 中文摘要: Rate constants directly measured by GC/MS-analyzed method for reduction of haloadamantanes by SmI2 in presence of HMPA and H2O were obtained. HMPA exhibits stronger catalytic effect than H2O does. The result of faster reaction rate of 1-bromoadamantane than that of 2-bromoadamantane can be used to confirm the formation of alkyl radical as the rate limiting step of this reduction.
- 英文摘要: --
- 中文關鍵字: Samarium diiodide; Haloadamantane
- 英文關鍵字: Samarium diiodide; Haloadamantane