- 作者: 王非,徐琰,高琳,冶保獻
- 作者服務機構: Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
- 中文摘要: Reactions of formylferrocene and 1,2-di-(o-aminophenoxy)ethane yield the novel bis(ferrocenyl) receptor (FcL). This compound has been characterized by IR, 1H NMR and elemental analysis. In addition, the electrochemical behavior of FcL was investigated in detail in 0.1 M tetra-n-butylammonium perchlorate (TBAP) + CH3CN by cyclic voltammetry (CV) and chronoamperometry. Its co-ordination properties with metal ions in acetonitrile were also studied. The FcL shows a two-wave behavior for H+, Cu2+, Zn2+ and Ni2+, but was unresponsive to Mg2+ and Ca2+. The maximum oxidation peak shift of about 250 mV was found for FcL in the presence of Cu2+, Zn2+ or Ni2+.
- 英文摘要: --
- 中文關鍵字: Biferrocenamine-based receptor; Electrochemistry; Molecular recognition
- 英文關鍵字: --