- 作者: 秦忠平 ; 周捷麗 ; 謝觀峻
- 作者服務機構: 陸軍軍官學校理化系
- 中文摘要: By means of ultraviolet and visible spectroscopy we have studied the catecholase activity of two binuclear copper(II) complexes of general formula(Cu/sub 2/REP(u-X)(Y)/sub 2/) (1, X=OH/sup -/ and Y=ClO/sub 4//sup -/; 2, X=Y=Cl/sup -/), REP= deprotonated 2,6-bis(1'-(4'-(2"-pyridyl)-2'-thiabutyl))-4-methylphenol. Both complexes promote catalytic autoxidation of 3,5-di-tert-butylcatechol (3,5-DTBC) to 3,5-di-tert-butylquinone (3,5-DTBQ) in methanol, but not in acetonitrile.
- 英文摘要: --
- 中文關鍵字: Binuclear Copper Complex; Spectral Analysis; Ultraviolet Spectroscopy; Visible Spectroscopy; Catecholase Activity
- 英文關鍵字: 雙核銅錯合物;光譜分析;紫外線光譜;可見光光譜學