- 作者： K. C. Mathur; M. K. Saxena
- 作者服務機構： Department of Organic Chemistry, University of Jodhpur, Jodhpur-342001, India
- 中文摘要：
The anhydride of cis-4-cyclohexene-1, 2-dicarboxylic acid was condensed with phenanthrene, acenaphthene and fluorine in the presence of anhydrous aluminium chloride to give the corresponding 2-(aroyl) cyclohex-4-ene-1-carboxylic acids. These keto acids when subjected to Wolf-Kishner reduction yielded the corresponding-2-(aryl) cyclohex-4-ene-1-carboxylic acids, which were then converted into their respective acid chlorides by refluxing with thionyl chloride in benzene. The acid chlorides in turn were
cyclised by anhydrous aluminium chloride in carbon disulphide to give the corresponding cyclic ketones. These cyclic ketones were then reduced by Wolf Kishner method to furnish the desired hydrocarbons, 2, 3-cyclohex-2’-ene-5 6-substituted cyclohexanes. - 英文摘要： --
- 中文關鍵字： --
- 英文關鍵字： --
