• 作者： Hwang, Bing-Joe; Shih, Yeong-Tay
• 中文摘要： 本文探討程序參數對鎳、磷之沈積速率與氫氣之析出速率之影響,並將結果與所提模式之理論分析作比較。所提次亞磷酸還原無電鍍鎳之兩相混合動力模式包括整體相之均勻相反應及基材上之非均勻相反應。由定性分析及動力分析,得知實驗結果與理論分析一致。對次亞磷酸還原無電鍍鎳之動力行為,所提兩相混合動力模式能比先前之模式提供一更深入之了解。
• 英文摘要： The effects of process parameters on the deposition rate of nickel, phosphorous, and evolution rate of hydrogen were investigated as well as a comparison being made with the theoretical analysis of the proposed model. The two- phase mixed kinetic model for hypophosphite reduced electroless nickel plating was developed, which includes homogeneous reactions in bulk solution and heterogeneous reactions on the substrate surface. The experimental results were sufficiently correlated well with the theoretical analysis, as indicated from both qualitative analysis and kinetic analysis. The proposed mixed kinetic model has provided a more complete insight into the kinetic behaviors of hypophosphite-reduced electroless nickel plating than the previous models have.
• 中文關鍵字： 兩相; 動力模型; 次亞磷酸鹽; 無電鍍鎳; 氧化鋁
• 英文關鍵字： Two Phase; Kinetic Model; Hypophosphite; Electroless Nickel; Alumina