- 作者: 翁榮源 ; 邱莉婷
- 作者服務機構: 靜宜大學應用化學系
- 中文摘要: Deprotonation, methylation, and air oxidation of polycyclic arenes coordinated to chromium(O), (.eta./sup 6/-arene)Cr(CO)/sub 3/, produced ring-methylated products with high selectivity and in good yield. This procedure gave 3-methylbenz[a]anthracene from (.eta./sup 6/-benz[a]anthracene)Cr(CO)/sub 3/, 3-methylphenanthrene from(.eta./sup 6/-phenanthrene)Cr(CO)/sub 3/, 2-acetyl-6-methylphenanthrene from (.eta./sup 6/-2-acetylphenanthrene)Cr(CO)/sub 3/, and 3,7,12-trimethylbenz[a]anthracene from (. eta./sup 6/-7,12-dimethylbenz[a]anthracene)Cr(CO)/sub 3/.
- 英文摘要: --
- 中文關鍵字: Polycyclic Aromatic Hydrocarbon (Pah); Tricarbonylchromium; Benzanthracene; Phenanthrene; Acetyl Phenanthrene; Methylation
- 英文關鍵字: 多環芳香碳氫化合物;三羰鉻;苯并;菲;乙醯菲;甲基化