- 作者: Behzad Zeynizadeh* and Karam Zahmatkesh
- 作者服務機構: Chemistry Department, Faculty of Sciences, Urmia University, Urmia 57159, Iran
- 中文摘要: Pyridine zinc tetrahydroborate, [(Py)Zn(BH4)2], as a new stable ligand-metal borohydride, is prepared quantitatively by complexation of 1:1 zinc borohydride and pyridine at room temperature. This reagent efficiently reduces different aromatic and aliphatic nitro compounds to their primary amines in refluxing THF. In addition, the reduction shows chemoselectivity for aliphatic nitro compounds over the aromatic nitro compounds.
- 英文摘要: --
- 中文關鍵字: Reduction; Zinc borohydride; Nitro compound; Chemoselectivity; Amine.
- 英文關鍵字: Reduction; Zinc borohydride; Nitro compound; Chemoselectivity; Amine.