- 作者: Lipshutz, Bruce H. ; Gross, Tim ; Buzard, Daniel J. et al.
- 作者服務機構: Dept. of Chemistry, Univ. of California, Santa Barbara, California, U.S.A.
- 中文摘要: Organozinc reagents FG-(CH/sub 2/)/sub n/ZnX containing electrophilic centers (FG) upon conversion to their corresponding zincates (FG-(CH/sub 2/)/sub n/ ZnMe/sub 2/Li) and in the presence of 5-8mol% MeCu(CN)Li, undergo 1,4-additions to cyclic conjugated enones. The intermediate zinc enolates can be trapped with aldehydes to afford products of three-component couplings.
- 英文摘要: --
- 中文關鍵字: Cuprate; Organzinc Reagent; Zincate; Three Component Coupling
- 英文關鍵字: 銅酸鹽;有機鋅試劑;鋅置換;三成分耦合