- 作者: 蔡秀娟 ; 鄭明珠 ; 彭旭明 等
- 作者服務機構: 台灣大學化學系
- 中文摘要: The title complex underwent ligand substitution by diphenylphosphine to form dicarbonyl [ P,P',S-(2,2- bis(diphenylphosphinomethyl)-1-phenylthiopropane ](diphenylphosphine)manganese(I) hexafluorophosphate (2) under photochemical conditions. The crystal structure of complex (2) was determined. The reaction was kinetically independent of the concentration of diphenylphosphine, so a first-order reaction.
- 英文摘要: --
- 中文關鍵字: Tripodal Phosphine; Photochemical Ligand Substitution; Crystal Structure; Diphenyl Phosphine; Complex
- 英文關鍵字: 光化學配位基取代反應;晶體結構;二苯膦;錯合物