- 作者: B. K. Puri; Ashok Kumar; A. L. J. Rao
- 作者服務機構: Department of Chemistry Indian Institute of Technology New Delhi- 110 016 (India)
- 中文摘要: The Polarographic behaviour of uranium and tellurium has been studied in the presence of increasing concentration of complex forming agent viz. .in.-caprolactam at pH 4.4 for U(VI) and at pH 10.0 for Te(IV) at .mu.=0.1M KNO/sub 3/. In both cases the waves have been found to be diffusion controlled and irreversible. The values of linetic parameters (.delta.n/sub a/ and K/sub f,h//sup 0/) have been calculated as a function of the ligand concentration. Method is suitable for the quantitative determination of these metals individually and simultaneously with the effect of diverse ions.
- 英文摘要: --
- 中文關鍵字: Uranium determination; tellurium determination; synthetic mixtures analysis; polarography; .in.-caprodactam
- 英文關鍵字: Uranium determination; tellurium determination; synthetic mixtures analysis; polarography; .in.-caprodactam