- 作者: 林聖賢; 潘貫
- 作者服務機構: Contribution from the Research Institute of Chemistry, National Taiwan University
- 中文摘要:
The reduction of Hg(II) by Ti(III) ions in aqueous solution of hydrochloric acid has been found to be of second-order with respect to the total concentrations of Hg(II) and Ti(III) ions,
-d[Ti/sup +++/]/sub t/ /dt=k[Ti/sup +++/]/sub t/[Hg/sup ++/]/sub t/.
The rate constant was found to be practically independent of the concentration of hydronium ion, but to be a function of that of chloride ion. The competing reactions of Ti+++ and TiCl++ with Hg++, HgCl+, HgCl3- and HgCl4= were inferred. The specific rate constants were calculated. - 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --