- 作者: 盧文芳 ; 汪炳鈞
- 作者服務機構: 清華大學化學系
- 中文摘要: Synthesis of DL-boivinose from reaction of 3-methyl-2- butenal and an allyl Grignard reagent followed by a chemo-, regio-, and diastereoselective ene reaction on a dienol intermediate with singlet oxygen, an ozonolysis, a protection reaction, and a chemoselective hydride reduction is described. The synthesis was completed in six steps with overall yield 29.7%.
- 英文摘要: --
- 中文關鍵字: Boivinose; Diastereoselective Ene Reaction; Synthesis; Grignard Reagent
- 英文關鍵字: 位向選擇烯反應;合成;格任亞試劑