- 作者: Yen, Shi-Chern
- 中文摘要: 本文提出氧化還原反應在流經孔隙性電極的一維模式,在孔隙性電極所得的總電流密度受到質量傳送、溶液導電度和電極動力學的影響。因此我們將總電流密度分成三個因子,分別為濃度有效因子,歐姆有效因子,以及在沒有濃度變化與歐姆阻力下平板的無因次電流密度。如此分割對判斷何種因素影響孔隙性電極的操作與設計甚有助益。
- 英文摘要: One-dimensional model of redox reaction in flow-through porous electrodes has been proposed. The total current density obtained is affected by the mass transport to the surface, the solution conductivity, and the electrode kinetics. Therefore it is divided into three factors, concentration effectiveness factor, ohmic effectiveness factor, and the dimensionless current density without concentration variations and ohmic resistance. With this splitting it would be helpful to distinguish which factor is crucial to the operation and design of the porous electrodes.
- 中文關鍵字: 孔隙性電極; 歐姆有效因子; 濃度有效因子; 氧化還原; 電極反應; 電流密度; 電極動力學
- 英文關鍵字: Porous Electrode; Ohmis Effectiveness Factor; Concentration Effectiveness Factor; Redox; Electrode Reaction; Current Density; Electrode Kinetic