- 作者: 蔣育澄
- 作者服務機構: School of Chemistry and Materials Science, Shaanxi Normal University, Xi’an, Shaanxi 710062, P. R. China
- 中文摘要: Densities have been measured for the CsCl-saccharide (D-glucose, D-fructose)-water systems at 298.15 K. These data were used to calculate the apparent molar volume of CsCl (VF,E) and the saccharides (VF,S), and the infinite dilution apparent molar volume VF,E0 and VF,S0 in the studied solutions. In addition, the standard transfer volume DtVf,E 0 of CsCl from water to aqueous saccharides solutions, and atVf,S 0 of saccharides from water to CsCl solutions have been evaluated and discussed using the structural interaction model. The volumetric interaction parameters for CsCl with saccharide in water were obtained and analyzed by the group additivity principle and the stereochemistry of the saccharide molecules.
- 英文摘要: --
- 中文關鍵字: Density; ?Apparent molar volume; ?Standard transfer volume; ?Volumetric interaction parameter; ?CsCl; ?Saccharide
- 英文關鍵字: --