• 作者： 吳裕文
• 作者服務機構： 高雄工學院化學工程系
• 中文摘要： The relative rates for the addition reactions of tert- butyl radical to 2-substituted allyl chlorides 1 have been determined. The correlation of log k/k/sub 0/, vs..sigma./sub m/ gives a .rho. value of 3.59 with correlation coefficient of 0.930. When the substituent CH/sub 2/Cl is excluded, correlation coefficient raises to 0.990 and .rho. value becomes 3.39. The large .rho. value and the deviation of relative rate of substituent CH/sub 2/Cl are discussed.
• 英文摘要： --
• 中文關鍵字： Substituent Effect; Butyl Free Radical; Allyl Chloride; Polar Effect; Nucleophilicity
• 英文關鍵字： 取代效應；丁基自由基；丙烯氯；極效應；親核性