- 作者: 洪永?*,翁英傑,吳國瑞
- 作者服務機構: Department of Chemistry and Biochemistry, National Chung Cheng University, Chia-Yi 62102, Taiwan, R.O.C.
- 中文摘要:
The ozonolysis of 1-substituted allyl silyl ethers or 1-substituted allyl carboxylates followed by treatment
with bases gave the corresponding α-silyloxymethyl- or α-acyloxymethyl-ketones in good yields. It
is proposed to proceed via the corresponding -silyloxy- or α-acyloxyaldehydes intermediates followed
by 1,4-group migration. The results of theoretical calculations are applicable to explain the experimental
results. - 英文摘要: --
- 中文關鍵字: Ozonides; α-Acyloxyaldehydes; α-Silyloxymethyl ketones; α-Acyloxymethyl ketones; Ene-diol rearrangement.
- 英文關鍵字: --