- 作者: 莊基德 ; 嚴嘉蕙 ; 吳獻仁
- 作者服務機構: 交通大學應用化學系
- 中文摘要: A new reaction involving an intramolecular Diels-Alder reaction of a furan diene with an allenyl ether dienophile followed by phenylthio group rearrangement was discovered. Treatment of the propargyl ethers 2a-c with t-BuOK in t-BuOH at 85.degree.C gave the phenylthio group rearrangement products 5a-c and 6a-c. A reaction involving an intramolecular Diels-Alder reaction of a furan diene with an allenyl ether dienophile followed by trialkylsilyl group rearrangement is also demonstrated.
- 英文摘要: --
- 中文關鍵字: Intramolecular Reaction; Furan; Allenyl Ether; Phenylthio Group Rearrangement; Trialkylsilyl Group Rearrangement; Diels-Alder Reaction
- 英文關鍵字: 分子內反應;喃;丙烯酯;苯硫基重組;三烷矽基;Diel-Alder反應