- 作者： Gialih Lin and Chin-Ping Lu
- 中文摘要： Conformational analysis of 1,2-di-O-octanoyl-ethylene-glycerol during aggregation by 600 MHz 1H NMR is described. In monomeric states, 1,2-di-O-octanoyl-ethylene-glycerol exists in 75% anti-conformer and 25% gauche-conformer. The first critical micelle concentration of 1,2-di-O-octanoyl-ethylene-glycerol is calculated to be 4.5 mM. In micellar states, 1,2-di-O-octanoyl-ethylene-glycerol exists in 25% anti-conformer and 75% gauche-conformer. When the concentration is greater than 10 mM, 1,2-di-O-octanoyl-ethylene-glycerol probably aggregates to become the larger micelle, micelle II. In the second micellar state, 1,2-di-O-octanoyl-ethylene-glycerol only exists in gauche-conformer.
- 英文摘要： --
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