- 作者: 胡聰成 ; 葉名倉
- 作者服務機構: 台灣師範大學化學系
- 中文摘要: The addition of reactive carbanions to tricarbonyl(.eta./sup 4/-1,3-diene)iron(0) complexes proceeded at -78.degree.C to give putative tricarbonyl(.eta./sup 1/,.eta./sup 2/-but-3-en-1-yl)iron(0) anion complexes and at 25.degree.C to produce postulated tricarbonyl(.eta./sup 3/-allyl)iron(0) anion complexes; trapping of reactive intermediates with dioxygen produced.gamma.,.delta.-unsaturated acids and allylic alcohols, respectively.
- 英文摘要: --
- 中文關鍵字: Diene Iron Complex; Unsaturated Acid; Allylic Alcohol; Carbanion
- 英文關鍵字: 二烯鐵錯合物;不飽合酸;烯丙基醇;碳陰離子