- 作者: Abdel-Aziz, Mahfouz A. ; Fahmy, Hussein M. ; Abdel-Azzem, Magdi et al.
- 作者服務機構: Dept. of Chemistry, Cairo Univ., Giza, Egypt
- 中文摘要: The polarographic reduction of a series of 2-aryl-hydrazono-2-cyanothioacetamides has been examined in 50% ethanolic buffer solutions. The obtained data indicate that these compounds are in the hydrazono form and that they are reduced to give an amino acid and the corresponding primary aromatic amine. A mechanism has been proposed and discussed. Recombination and dissociation rate constants(k/sub r/) and (k/sub d/) have been computed using the appropriate spectrophotometric, potentiometric and apparent acid equilibrium constants.
- 英文摘要: --
- 中文關鍵字: Electroreduction; Arylhydrazonocyanothioacetamide; Buffer Solution; Equilibrium Constant
- 英文關鍵字: 電化還原;芳基亞□基氰基硫乙醯胺;緩衝溶液;平衡常數