- 作者: 吳芳枝 ; 王素蘭 ; 劉育良 等
- 作者服務機構: 清華大學化學系
- 中文摘要: (Cu(C/sub 8/H/sub 22/N/sub 4/))(ClO/sub 4/)/sub 2/.bcdot.H/sub 2/O, M/sub r/=454.80, orthorhombic C222/sub 1/, a=15.481(5), b=7.404(1), c=14.827(3).ANG., V=1699.5(8).ANG./ sup 3/, Z=4, D/sub x/=1.78g/(cm/sup 3/), .lambda.(MoK./ sub.alpha./)=0.71073. ANG., .mu.=16.5cm/sup -1/. F(000)=940, T=22.degree.C, R=6.86%, R/sub W/=7.66% for 820 observed reflections (I>2.5.sigma.(I)). The coordination number for the copper(II) ion is five, and the coordination geometry about copper(II) ion is a buckled square pyramid with the tetraamine equatorial and a perchlorate ion axial. The tetraamine is coordinated in a square-planar manner with slight tetrahedral distortions. The four Cu-N distances span a very narrow range, 1.990(10)-1.994(14).ANG.
- 英文摘要: --
- 中文關鍵字: Molecular Structure; Perchlorato(2,5,8,11-Tetraazadodecane) Copper(Ii) Perchlorate Monohydrate
- 英文關鍵字: 分子結構