- 作者: Fa-Yen Lee and Jia-Liang Zhu*
- 作者服務機構: Department of Chemistry, National Dong Hwa University, Soufeng, Hualien 974, Taiwan, R.O.C.
- 中文摘要: A new procedure for the regiocontrolled synthesis of α-(phenylsulfanyl) carbonyl compounds has been developed, making use of lithium naphthalenide induced reductive sulfenylation of α-cyano carbonyl compounds as a key operation. Through this protocol, a variety of α-(phenylsulfanyl) carbonyl compounds has been prepared in moderate to high yields. The completely regioselective sulfenylation was observed in most of the cases.
- 英文摘要: --
- 中文關鍵字: Nitriles; Sulfur; Lithium naphthalenide; Reductive sulfenylation.
- 英文關鍵字: --