- 作者: 洪豐裕
- 作者服務機構: Department of Chemistry, National Chung-Hsing University, Taichung 40227, Taiwan, R.O.C.
- 中文摘要: Reaction of an alkyne-bridged dicobalt complex, [Co2(CO)6(m-Me3SiCoCpy)] 4, with bis(diphenylphosphino)methylene (DPPM) or bis(diphenylphosphino)ethylene (DPPE) in THF at 55 oC yielded a DPPM or DPPE doubly bridged dicobalt compound, [{m-P,P-PPh2CH2PPh2}Co2(CO)4(m-Me3SiCoCpy)] 5 or [{m-P,P-PPh2CH2CH2PPh2}Co2(CO)4(m-Me3SiCoCpy)] 6. Compound 5 and 6 were characterized by spectroscopic means as well as X-ray crystal structure determination.
- 英文摘要: --
- 中文關鍵字: Alkyne-bridged dicobalt complex; ?Bis(diphenylphosphino)methylene; ?Bis(diphenylphosphino)ethylene; ?Hydrogen bonding.
- 英文關鍵字: --