- 作者: 周大新 ; 韋錦全 ; 吳東昆
- 作者服務機構: 中正大學化學系
- 中文摘要: Oxidative ring opening reactions enabled disassembly of the cage structure of the title compound. Stepwise oxidations were achieved through radical intermediates using lead tetracetate and iodine. The regio-selectivity of bond fission is rationalized by comparing the relative strains of each bond. Multiple cleavages of C-C bond were accomplished by photolysis with HgO and iodine under UV. The oxidative effect of Ce(IV) ion on a cage-shaped diketone is examined. New skeletons of polyquinanes are obtained from these reactions.
- 英文摘要: --
- 中文關鍵字: Cage-Shaped Hydrocarbon; Ring Opening Reaction; Oxidation; Regioselectivity; Photolysis
- 英文關鍵字: 籠形碳氫化合物;開環反應;氧化;特定位向反應;光解