- 作者: Chou, Tse-Chuan; Liang, Chin-Hwang
- 中文摘要: 利用高分子載體製備之鈷型不均勻化均勻觸媒催化苯甲醛氧化反應之動力學參數在本文給予求得. 有關之動力學參數的常數與活化能均獲得其值. 利用抑制法求得熱起始與觸媒起始氧化步驟之動力學參數, 其相對之活化能與常數也在本文中獲得.
- 英文摘要: Kinetic parameters of the oxidation of benzaldehyde using heterogenized homogeneous Co(III) as catalyst were evaluated. Values of apparent activation energies and preexponential factors for the corresponding group kinetic parameters were obtained. An inhibitor method was introduced to evaluate the kinetic parameters of thermal and catalytic initiation of benzaldehyde oxidation. The activation energies and preexponential factors of the thermal and catalytic initiation were also evaluated in this work.
- 中文關鍵字: 動力學參數; 氧化; 苯甲醛; 高分子載体鈷(III)觸媒; 抑制法
- 英文關鍵字: Kinetic Parameters; Oxidation; Benzaldehyde; Polymer Supported Co(Iii); Inhibitor Method