- 作者: 羅俊光
- 作者服務機構: 國立清華大學原子科學研究所
- 中文摘要: 以光化學方法研究高熱氚原子與氣的反應,利用波長 1743 /1745 使含氚水分解而得 1.6 eV 之氚原子,該氚原子與氚化甲烷(CD )之抽成反應得 DT 產率為2.5%與氣氚氣(D )之抽成反應得 DT 產率為20.4%到25.9%,其他氚標誌化合物為CD T,C D T,C D T和C D T等,本研究係利用放射性氣層分析儀作分餓與定最的方法。
- 英文摘要: The reaction of hot tritium atoms with deuterated compounds have been studied by photochemicalmethod. The energetic tritium atom with kinetic energy of 1.6 eV is produced by photolysis of tritiatedwater vapor at 1743 ∕1745 wavelengths. The abstraction yield of DT is around 2.5% in H O-T/CD system and 20.4% to 25.9% in H O-T/D system. The other tritiated hydrocarbons are CD T, C D T,C D T and C D T. All tritium labeled compounds were assayed by radio-gas chromatography.
- 中文關鍵字: hot tritium atom; CD4; D2; abstraction; substitution
- 英文關鍵字: --