- 作者: 周善行 ; 徐健宏
- 作者服務機構: 輔仁大學化學系
- 中文摘要: Hydride abstraction of tricarbonyl [ .eta./sup 4/-1-(phenylsulfonyl)-1,3-cyclohexadiene ] iron(0) complex 2 with Ph/sub 3/C/sup +/PF/sub 6//sup -/ regiospecifically provided the title compound 3 in excellent yield. Cationic complex 3 could react with a variety of nucleophiles in good yields. Soft nucleophiles prefer to attack at the C-5 position, whereas hard nucleophiles such as methyllithium and the enolate of ethyl acetate gave the C-5 as well as the C-2 addition products. Some synthetic applications of the addition products were also studied.
- 英文摘要: --
- 中文關鍵字: Iron Complex; Diene; Nucleophilic Addition Reaction; Sulfone
- 英文關鍵字: 鐵錯合物;雙烯;親核性加成反應;