• 作者： 邱華樞; 吳謀泰; 唐定國; 許文榮; 潘萬幸; 何世延
• 作者服務機構： 中山科學研究院; 國立清華大學化學研究所
• 中文摘要： 1,3-J二烯與過氧化氫於液相以波長大於2500A的紫外光照射，研究其光化學聚合反應。過氧化氫經光解生成氫氧
  基，引發丁二烯的聚合，並生成了以氫氧基為終端的聚合產物。戊烷、苯、甲醇、乙醇、異丙醇、四氫?喃及丙酮等作
  為溶劑。並發現了有些溶劑頗有影響。並對聚合物的平均分子量，細微結構、官能基等性質也作了測定。
• 英文摘要： Photochemical polymerization reactions in 1,3-butadiene-HO liquid mixtures have been studiedat wavelengths＞2500A. Hydrogen peroxide is photodecomposed to form hydroxyl radical which mayinitiate the polymerization of butadiene with hydroxyl terminated polybutadiene as the products. Pentane,benzene, methanol, ethanol, isopropanol, tetrahydrofuran, and acetone are added as solvents and somesolvent effects are observed. The average molecular weight, microstructure, and functionality of the hy-droxyl terminated polybutadiene are determined.
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