- 作者: 郭素惠; 張如瑋; 李遠鵬
- 作者服務機構: Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300, R.O.C.
- 中文摘要: Visible chemiluminescence in the 5800-6600A region was observed from the Ca+Cl/sub 2/ reaction in an argon matrix. The longer wavelength doublet progression is assigned as the A/sup 2/II/sub 3/2,1/2/.arrlr. X/sup 2/.SIGMA./sup +/ transition of CaCl. Both transitions showed very small matrix shifts in the T/sub 0/ values. A weak band at 17185cm/sup -1/ was assigned as either the E/sup 2/.SIGMA..arrlr. B/sup 2/.SIGMA./sup +/ or the a/sup 4/.SIGMA./sup +/.arrlr. A/sup 2/II transition of CaCl. Ca atomic emission at 4232 and 6574A was also observed and it was attributed to the energy transfer processes from excited CaCl radicals.
- 英文摘要: --
- 中文關鍵字: CaCl; chemiluminescence; matrix
- 英文關鍵字: CaCl; chemiluminescence; matrix