- 作者: 劉瑞雄
- 作者服務機構: 國立清華大學化學系
- 中文摘要: 線型過渡金屬戊二烯化合物的合成方法在文中將詳細討論,1-氯-2,4-戊二烯可以經由氧化加成得到不同戊二烯之結構化合物。此類化合物化學及構造模型的整理將以 , 及 為依歸,另外晶體結構以闡明其化學將整理之。
- 英文摘要: Synthesis of transition-metal acyclic pentadienyl complexes from 1-halo-penta-2,4-diene is described.The latter is a convenient reagent for numerous metal-dienyl compounds because it can be oxidativelyadded to low-valent metal complexes, of which examples are given in this paper. Structural patterns andcnemicai reactivity or tnese complexes are summarizecd according to tne , and categories. Crystal-lographic data for further characterization of their chemistry are also described.
- 中文關鍵字: transition-metal-dienyl-complexes
- 英文關鍵字: --