- 作者: 張瑞麟 ; 江志強 ; 謝珮真 ; 張煥正 ; 林聖賢
- 作者服務機構: 中央研究院原子與分子科學研究所
- 中文摘要: A theory of vibrational predissociation spectroscopy is developed based on the adiabatic approximation that separates the oscillations of the high frequency vibron and low frequency phonon. We find that some properties such as dissociation energy and the number of phonon modes have significant influence on the temperature dependent spectra. Thus a comparison between the present theory and experiment would be a useful approach in determining these properties.
- 英文摘要: --
- 中文關鍵字: Predissociation; Adiabatic Approximation; Vibron; Spectral Bandshape; Saddle-Point Method; Vibrational Predissociation Spectroscopy; Dissociation Energy
- 英文關鍵字: 預先解離;絕熱近似值;電子振動;光譜波形;馬鞍標點法;振動預先解離光譜;解離能