- 作者: 張宗仁
- 作者服務機構: Department of Chemistry, National Sun Yat-Sen University, Kaohsiung, Taiwan, R.O.C.
- 中文摘要: The insertion reaction of CS2 with Mg(NR2)2 (R= Et, iPr), MgR¢2 (R¢= Et, Ph) and R2MgBr (R2= iPr, Ph) respectively lead solid products, Mg(S2CNR2)2(THF)n (1: R= Et, n=2; 2: R= iPr, n=1), Mg(S2C¢R)2(THF)2 (3: ¢R= Et, 4: ¢R= Ph), BrMg(S2C2R) (THF)3 (5: 2R= iPr, 6: 2R= Ph) in which the inserted carbon disulfides act as terminal chelating ligands. These compounds were characterized with 1H, 13C NMR, IR spectroscopy, mass spectrometry, elemental analyses, and X-ray crystallography.
- 英文摘要: --
- 中文關鍵字: Magnesium thiocarbamate; ?Magnesium thiocarboxylates; ?CS2 insertion.
- 英文關鍵字: --