- 作者: Tzuen-Yeuan Lin, Ming-Ren Fuh and Shih-Chun Chang
- 中文摘要: Rate constants directly measured from GC-analyzed method for SmI2 reduction of alkyl halides were obtained. The rates increase in the orders of primary, secondary, tertiary RX and RCl < RBr < RI as expected. 2-Heptanone was chosen as the partner of alkyl halide in the samarium Barbier reaction. In the absence of HMPA, the reaction orders of alkyl halide and ketone were determined as first and zero order, respectively.
- 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --