- 作者: 劉緒宗
- 作者服務機構: Department of Chemistry, National Taiwan University, Taipei, Taiwan 106, R.O.C.
- 中文摘要: Palladium complexes [(P~N~O)PdR]BF4 containing imine-phosphine-ether tridentate donor were prepared. The behavior of an ether donor, a hemi-labile one, influences the coordination mode of a carbon ligand around the metal center. Reaction of excess styrene with [(P~N~O)PdMe]BF4 results in the formation of [(P~N~O)Pd(h3-CH(CH3)C6H5)]BF4, which is characterized by spectral and crystal structural determination. Copolymerization of olefin and carbon monoxide catalyzed by [(P~N~O)PdMe]BF4 is addressed.
- 英文摘要: --
- 中文關鍵字: Imine-phosphine; Tridentate; Palladium; Polymerization.
- 英文關鍵字: Imine-phosphine; Tridentate; Palladium; Polymerization.