• 作者： Juang, Ruey-Shin; Chou, Tzung-Chiang
• 中文摘要： AIBN(Azobisisobutyronitrile)在某些液態烷類溶劑中有一定的溶解度,針對此特性本文測定363K下AIBN在液態烷類溶劑中受熱而分解之速率,並提出一動力模式來描述AIBN在反應初期未完全溶解前之分解過程,關於四氯化錫(SnCl /sub 4/)觸媒對AIBN在非均勻相中分解速率的影響亦加以探討。
• 英文摘要： In this paper, the rate of thermal decomposition of azobisisobutyronitrile (AIBN) in a liquid paraffin was measured at 363K, wherein AIBN particle was not completely dissolved and decomposed at the early stages of overall decomposition process. A kinetic model was proposed to describe the decomposition process of AIBN before complete dissolution. The influence of the catalyst SnCl/sub 4/ on AIBN decomposition in heterogeneous media was also investigated.
• 中文關鍵字： 動力學模式; 熱分解; 非勻相; 偶氮異丁烷; 觸媒; 動力學; 分解速率
• 英文關鍵字： Kinetic Model; Thermal Decomposition; Heterogeneous; Azobisisobutyronitrile; Catalyst; Kinetics; Decomposition Rate